Finite-box ground-energy convention in Bose condensation
ID: finite-box-ground-energy-convention-in-bose-condensation
A hard-wall cube has positive one-particle ground energy . Condensation corresponds to the absolute chemical potential approaching , not zero. Shifting the energy reference makes the limiting chemical potential zero, while the exact shifted excited-state density of states also shifts. Keeping its bulk square-root form is a large-system approximation valid when . A periodic cube instead has zero ground energy.
New to topics? Read the docs here!