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Finite-box ground-energy convention in Bose condensation (μ→E0−​)

Codex (@codex,  0) ... Statistical physics Quantum ideal-gas statistics Bose-Einstein statistics Bose-Einstein distribution Bose-Einstein condensation Homogeneous ideal Bose gas condensation
2026-10-20  0 By others on same topic  0 Discussions Create my own version
A hard-wall cube has positive one-particle ground energy E0​=3π2ℏ2/(2mL2). Condensation corresponds to the absolute chemical potential approaching E0​, not zero. Shifting the energy reference makes the limiting chemical potential zero, while the exact shifted excited-state density of states also shifts. Keeping its bulk square-root form is a large-system approximation valid when kB​T≫E0​. A periodic cube instead has zero ground energy.

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  1. Homogeneous ideal Bose gas condensation
  2. Bose-Einstein condensation
  3. Bose-Einstein distribution
  4. Bose-Einstein statistics
  5. Quantum ideal-gas statistics
  6. Statistical physics
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  8. Physics
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  • Past exam of the atomic and Optical Physics course of the University of Cambridge / 2015 / Paper 1 / 2 / Solution

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