 Formula unit

A formula unit is a specified compositional accounting entity for a chemical substance that need not consist of discrete molecules. For ordinary crystalline $\mathrm{NaCl}$, one formula unit counts one sodium ion ${\mathrm{Na}}^{+}$ and one chlorine ion ${\mathrm{Cl}}^{-}$; it does not identify an isolated pair within the crystal. Cohen et al., IUPAC Green Book, 3rd ed., §2.10.1(iii)(b), p. 51 defines a formula unit as a specified group of chemical atoms, rather than a unit of measurement. An amount of substance of one mole of $\mathrm{NaCl}$ formula units therefore corresponds to one mole of each kind of ion.