Hamaker estimate of liquid surface tension

ID: hamaker-estimate-of-liquid-surface-tension

For two liquid half-spaces, integrate the magnitude of a dispersion attraction per area from a molecular contact cutoff to infinity. The work per area is . Because cleavage creates two interfaces, each has the displayed surface tension in this approximation. The cutoff is essential: a continuum attraction cannot describe atomic overlap and short-range repulsion. This estimate neglects interfacial entropy, detailed density profiles and nonadditive interactions, and it cannot replace the metallic bonding or hydrogen bonds that dominate some liquids' cohesion.

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