Parabolic variational trial for a particle in a box
ID: parabolic-variational-trial-for-a-particle-in-a-box
For an infinite square well of width , the normalized trial obeys both Dirichlet boundary conditions and has no interior nodes of a wavefunction. Its kinetic energy isThe ratio to the exact ground-state energy is . Its expansion in the normalized sine eigenfunctions has coefficients for odd and zero for even . This supplies a concrete check of the quantum variational principle and shows that a small energy error can coexist with excited-state admixtures.
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