Solution

ID: past-exam-of-the-chemistry-a-course-of-the-university-of-cambridge/2021/paper-2/a9/a/i/solution

For the free electron model, the Fermi energy is the highest occupied one-electron energy at zero temperature, measured relative to the bottom of the free-electron band. The occupied wavevectors fill a disk in two dimensions or a sphere in three dimensions. The radius is the Fermi wavevector , with
Each allowed wavevector has two spin states. At nonzero temperature, the Fermi-Dirac distribution rounds the occupation boundary; the zero-temperature Fermi energy remains a useful density-defined scale and should not be defined as the thermal energy .

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