Solution

ID: past-exam-of-the-chemistry-a-course-of-the-university-of-cambridge/2025/paper-1/a1/b/ii/solution

The decisive observation is that is itself an eigenfunction:
On the regular Legendre polynomial domain, integration by parts has endpoint factor , so the boundary form vanishes for regular functions at . The interval alone is not an endpoint condition; regularity is the usual condition selecting the Legendre polynomials. Their eigenvalues are , and the normalized function is
Therefore
Equivalently, the Hermitian operator identity gives , and nondegeneracy leaves only one possible nonzero coefficient. The unnormalized function has squared norm , consistent with this coefficient.

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