 Solution

The Bloch vector representation of a qubit density matrix is $\rho =\frac{1}{2}(I+r_{x}X+r_{y}Y+r_{z}Z)$, where $r_j=\mathrm{Tr}(\rho {\sigma }_j)$ and $|\mathbf{r}|\le 1$. Pure states have $|\mathbf{r}|=1$, while the origin represents the maximally mixed state $I/2$, not a pure state.

For the two preparations, direct evaluation of the Pauli matrices givesTheir dot product is $-1/2$, so their Bloch vectors meet at angle $\boxed{2\pi /3}$, or $120$ degrees. This is the angle between Bloch vectors; the angle determined by the modulus of the Hilbert-space overlap is different.

Completeness of the POVM requires $E_3=I-E_1-E_2$. In the computational basis, subtraction givesAn overall phase of ${\varphi }_3$ is immaterial. The matrix has eigenvalues $2/3$ and zero, so it is positive; together with $E_1,E_2$ it is a valid trine qubit POVM.

The Born rule gives $\mathrm{Pr}(j\mid {\rho }_i)=\mathrm{Tr}(E_j{\rho }_i)=\frac{2}{3}|⟨{\varphi }_j|{\psi }_i⟩{|}^2$. The conditional probabilities areOutcome one identifies ${\rho }_2$, since ${\varphi }_1$ is orthogonal to ${\psi }_1$; outcome two identifies ${\rho }_1$, since ${\varphi }_2$ is orthogonal to ${\psi }_2$. Outcome three is inconclusive. If Alice's prior probability for ${\rho }_1$ is $q$, the unconditional outcome probabilities are $(1-q)/2$, $q/2$, and $1/2$ respectively. Because outcome three has the same likelihood for both preparations, it leaves the prior odds unchanged. Bob's conclusive identification succeeds with probability one half and is never wrong; he does not identify the state on the inconclusive trials. This is unambiguous quantum state discrimination.