Solution

ID: past-exam-of-the-mathematics-course-of-the-university-of-cambridge/2007/ii/paper-4/33a/solution

Label the two displacements in cell by , with cell length . Choose the spring within a cell and the spring between cells. The equations are
A Bloch wave gives a two-by-two eigenvalue problem, whose determinant is
Thus the alternating-spring chain dispersion relation is
Periodic boundaries require , so modulo . There are distinct wavenumbers in the Brillouin zone and two branches, accounting for modes. The minus branch is acoustic, with zero frequency and in-phase motion at the centre; the plus branch is optical, with opposite cell displacements.
Expanding the square root near zero gives
At the zone boundary the square root is , so the acoustic maximum is and the optical minimum is . The frequency gap is therefore
Quantizing each harmonic mode gives phonons, bosonic excitations of energy and crystal momentum defined modulo a reciprocal lattice vector. Their group velocity is ; acoustic phonons carry long-wavelength sound, while optical phonons have a nonzero centre frequency. There is one longitudinal polarization per branch here, and phonon number is not conserved in thermal equilibrium.

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