Solution

ID: past-exam-of-the-mathematics-course-of-the-university-of-cambridge/2013/ib/paper-2/17b/i/solution

The time-independent Schrodinger equation gives the even interior wavefunction , with . Outside, normalizability of a bound state requires , with .
Continuity of the wavefunction and its derivative at gives and . A nonzero solution cannot have , so division gives
At the formally allowed endpoint , the even interior solution is constant; derivative matching would force the exterior amplitude to vanish, leaving the zero solution. Nontrivial bound states therefore have . The matching formula is the even-state condition for a finite square well.

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