Past exam of the mathematics course of the University of Cambridge / 2013 / ib / Paper 2 / 17B / i / Solution

The time-independent Schrodinger equation gives the even interior wavefunction $\psi =A\cos (\alpha x)$, with ${\alpha }^2=2m(U+E)/{\hslash }^2$. Outside, normalizability of a bound state requires $\psi =C{e}^{-\beta (|x|-l)}$, with ${\beta }^2=-2mE/{\hslash }^2$.

Continuity of the wavefunction and its derivative at $x=l$ gives $C=A\cos (\alpha l)$ and $-\beta C=-\alpha A\sin (\alpha l)$. A nonzero solution cannot have $\cos (\alpha l)=0$, so division givesAt the formally allowed endpoint $E=-U$, the even interior solution is constant; derivative matching would force the exterior amplitude to vanish, leaving the zero solution. Nontrivial bound states therefore have $-U<E<0$. The matching formula is the even-state condition for a finite square well.