Solution

ID: past-exam-of-the-mphil-in-micro-and-nanotechnology-enterprise-course-of-the-university-of-cambridge/2018/paper-1/section-a-iii/6/i/solution

A thermoelectric generator uses the Seebeck effect: a maintained temperature difference across suitable conductors produces an open-circuit electromotive force. For a pair of legs,
when the effective Seebeck coefficient is approximately constant. Repeated p- and n-type legs are usually connected electrically in series and thermally in parallel.
Connecting a load lets part of the heat flowing from the hot side to the cold side become electrical power. Both a heat source and a cold-side heat-removal path are necessary: a uniformly warm device with no maintained temperature difference supplies no sustained output. Internal electrical resistance, heat leakage, contact losses and the finite temperature difference reduce the harvested power; the converter is a heat engine rather than a source of energy from temperature alone.

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