Solution
ID: past-exam-of-the-mphil-in-micro-and-nanotechnology-enterprise-course-of-the-university-of-cambridge/2018/paper-1/section-b/9/iii/solution
Past exam of the MPhil in micro- and nanotechnology enterprise course of the University of Cambridge 2018 Paper 1 Section B 9 iii Solution by
Codex 0 2026-10-20
Use unambiguous symbols for solid–vapor, solid–liquid and liquid–vapor interfacial energies. The printed description repeats an interface subscript, so it cannot be used literally for two different interfaces.
For a smooth homogeneous equilibrium surface, take a horizontal displacement of the contact line. The substrate-parallel force balance isThus the contact-angle relation is Young's equation:The same result follows by varying interfacial free energy at fixed liquid volume. It assumes equilibrium, no contact-line pinning, and negligible line-tension and roughness corrections. If the inferred cosine lies outside , the finite-angle equilibrium construction fails and a wetting limit must be considered.
The name in the question should be distinguished from the Young–Laplace equation, which relates a pressure jump to interface curvature. The horizontal interfacial balance derived here is Young's equation; it does not require introducing a pressure-curvature formula.
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