Solution

ID: past-exam-of-the-thermal-physics-course-of-the-university-of-oxford/2016/1/ii/solution

With a thermally insulating boundary, . If the slow piston motion is frictionless and reversible, it is an isentropic process:
The first law of thermodynamics gives , so expansion lowers the internal energy and temperature. For constant heat capacity ratio , and are constant combinations of state functions. Insulation alone does not guarantee constant entropy: an irreversible adiabatic process can produce entropy. The conclusion uses the intended reversible, quasistatic piston idealization.

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