 Postulates of quantum mechanics

For an isolated quantum system, pure states are normalized rays in a complex Hilbert space, observables are self-adjoint operators, and their probabilities obey the Born rule. A spectral projector $P_a$ has outcome probability $⟨\psi |P_a|\psi ⟩$; an ideal repeatable projective measurement has conditional state $P_a\psi /\sqrt{⟨\psi |P_a|\psi ⟩}$. The Schrödinger equation specifies continuous unitary evolution between such ideal measurements, given a Hamiltonian operator. General measurements need not have the projective state-update rule.

Composite systems use the tensor product of their state spaces. Identical particles additionally obey the bosonic or fermionic exchange symmetry appropriate to their species. The photoelectric effect, Davisson–Germer experiment and double-slit experiment motivate energy quanta, matter-wave phases and probability interference, respectively; these experiments constrain the framework but do not separately prove every abstract postulate or specify every system's Hamiltonian.