 Shot noise departures from Poisson statistics

The Fano factor $F_T$ compares count variance with its mean over a specified gate. For a stationary unidirectional stream with fixed charge $q$, finite count second moments, and a generalized autocovariance with finite integral so that the long-gate limit exists,The zero-frequency relation concerns the continuous fluctuation spectrum, excluding the mean spectral line. It follows by writing $\mathrm{Var}(Q_T)$ as the double integral of the current autocovariance; for long $T$, its leading term is $T{S}_I^{(2)}(0)$. A finite-gate $F_T$, a frequency-dependent ratio $S_I^{(1)}(f)/(2qI)$, and a factor inferred from one filtered variance are not interchangeable. The last is weighted by the instrument's $|K(f){|}^2$.

Two original counting counterexamples show why electric charge discreteness is insufficient. In $n$ independent time slots, transfer one charge with probability $p$ in each slot: the binomial distribution gives mean $np$, variance $np(1-p)$ and Fano factor $1-p$. A random common origin for the slots removes a preferred time origin; the long-gate factor remains $1-p$. Alternatively, if independent Poisson process bursts each transfer exactly two charges, then $N_T=2M_T$ gives $\mathrm{Var}(N_T)=2\mathbb{E}[N_T]$ and factor $2$. Both count individual charges; only the first model allows at most one per slot, and the second groups them in pairs.

Consequently $2qI$ is a reference for independent unidirectional arrivals, not a universal noise law for all electrical conductors. Correlations, charge multiplication, and bidirectional transfer require a more specific model. For example, independent opposite streams with positive current magnitudes $I_{+}$ and $I_{-}$ have net mean $I=I_{+}-I_{-}$ but one-sided fluctuation spectrum $2q(I_{+}+I_{-})$. Using $2q|I|$ would miss their fluctuations when the net current is small. At thermal equilibrium, the full transport model must also respect thermal electrical noise; adding unrelated phenomenological formulas can double count the same underlying transfers.