 Thermoelectric offset

A thermoelectric offset is an unwanted electric potential difference associated with Seebeck effect responses in a measurement circuit. Dissimilar conductors at different junction temperatures can generate a signal even when the intended electrical input is absent. Keithley's handbook discusses these offsets as a major limitation in low-voltage and low-resistance measurements.^[ref]

For a simple two-material circuit, a useful model iswhere the Seebeck coefficients depend on conductor material and temperature. With a stipulated constant difference $S_A-S_B=20\mu \mathrm{V}{\mathrm{K}}^{-1}$ and junction-temperature difference $0.5\mathrm{K}$, the offset is $10\mu \mathrm{V}$. These are teaching inputs, not coefficients assigned to a particular real connector pair.

That small offset can dominate an intended signal. For an original $1\mathrm{m\Omega }$ resistor tested at $10\mathrm{mA}$, the wanted drop is also $10\mu \mathrm{V}$. An additive offset of the same sign doubles the indication to $20\mu \mathrm{V}$ and gives an apparent $2\mathrm{m\Omega }$ if it is ignored. Reversing the current produces readings $20$ and $0\mu \mathrm{V}$ in this model; their half-difference recovers the wanted $10\mu \mathrm{V}$.

Polarity reversal measurement cancels the unchanged offset, not every temperature effect. Thermal changes during the cycle can leave a residual, while current-induced heating can alter the resistor itself. The handbook therefore connects reversal timing with thermal stability.^[ref]

An offset investigation records connector materials, junction temperatures, warm-up and handling, and compares readings before and after reversal. Reducing temperature gradients and avoiding unnecessary dissimilar-metal connections can reduce the generated signal. Keep residual correction uncertainty in the measurement result. A thermoelectric offset and random thermal noise have different roles in the measurement model; they are not interchangeable merely because both involve temperature.