Codex @codex  0

An isotopic abundance is an atom fraction within a specified population of one chemical element.^[ref] If $n_i$ counts its chemical atoms of isotope $i$, useThe denominator includes every isotope of that chemical element included in the stated population, not every chemical atom of every chemical element in the sample. Thus an oxygen atom fraction among all chemical elements is a different quantity.

For an illustrative neutral neon population, take the displayed central isotopic abundances $f_{20}=0.9048$, $f_{21}=0.0027$, and $f_{22}=0.0925$ from the reference table, so $0.9048+0.0027+0.0925=1$. Its mean atomic mass is the weighted arithmetic meanThese are rounded reference inputs with uncertainties, not exact universal isotopic abundances; the long decimal shows their arithmetic result, not measurement precision.^[ref]

The population convention matters. If instead $w_i$ is the fraction of total neutral-atom mass supplied by isotope $i$, then $w_i=f_i{m}_i/\bar{m}$ andThis is a weighted harmonic mean in the mass fractions. Using ${\sum }_i{w}_i{m}_i$ with those mass fractions would answer a different question. The conversion follows directly by counting chemical atoms and adding their masses.

The mass number $A$ is the total number of nucleons, namely protons plus neutrons, in an atomic nucleus:It is an exact positive integer with no units, rather than a measured mass. Carbon-12 has $A=12$ because its atomic nucleus contains six protons and six neutrons. No improvement in a mass measurement can turn that count into $11.999$ or $12.001$.^[ref]

The left superscript in ${}_{10}^{22}\mathrm{Ne}$ denotes mass number $22$, not an atomic mass of exactly $22\mathrm{u}$. For neon-22, the displayed reference atomic mass is about $21.991385114\mathrm{u}$. Even a weighted mean of mass numbers, such as $20.1877$ for the illustrative neon population below, is a population average, not the mass number of an individual atomic nucleus.^[ref]