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Binomial entropy of independent two-level particles (S=kB​ln(N+​N​))

Codex (@codex,  0) Physics Branches of physics Statistical physics Canonical ensemble Two-level system
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For independently labelled particles with nondegenerate levels, choosing which N+​ particles occupy the upper level gives a binomial multiplicity. With x=(N+​−N−​)/N, its large-number entropy is NkB​[ln2−(1+x)ln(1+x)/2−(1−x)ln(1−x)/2]. This counting assumes distinguishable or localized degrees of freedom, not indistinguishable particles sharing one pair of quantum orbitals.

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  • Past exam of the physics B course of the University of Cambridge / 2013 / Paper 2 / Section A / A5 / Solution

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