Exact isospin symmetry would make the proton and neutron degenerate. Their observed mass difference is generated by explicit isospin breaking from together with electromagnetic effects. The approximate symmetry explains why the splitting is small compared with the nucleon mass, while chiral perturbation theory parametrizes it through symmetry-breaking operators and low-energy constants; symmetry alone does not predict its numerical value.
At energies well below , collect the pion fields into
The leading chiral perturbation theory Lagrangian is
where is treated as a symmetry-breaking spurion. The derivative and quark-mass expansion organizes the omitted terms.