If relic particle number and reference-gas entropy are separately conserved in a comoving volume, their ratio is constant. A decay or entropy injection can change it. The reference entropy is that of the specified thermal sector, not necessarily the entropy of the decoupled relic itself.
A species freezing out while relativistic retains its thermal comoving number. If it is nonrelativistic today, . Comparing with photons gives . An upper density fraction therefore bounds its mass inversely with its relic number density. The relation does not apply unchanged to a species whose abundance is depleted by nonrelativistic annihilation.

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