Decay amplitude ($\mathcal{M}(i\to f)$)

The invariant decay amplitude is the transition matrix element for one incoming particle and a specified on-shell final state, with the overall momentum delta function factored out. For covariantly normalized states, write the connected S-matrix element as $i(2\pi {)}^4{\delta }^4(p_i-p_f)\mathcal{M}(i\to f)$. Its overall phase does not affect the decay width. The rate is $\Gamma =(2M_i{)}^{-1}{\sum }_{\mathrm{spins}}\int d{\Phi }_f|\mathcal{M}{|}^2$, with the initial spin average included when the initial state is unpolarized. For a spin-zero parent and an angle-independent two-body amplitude, the two-body Lorentz-invariant phase space gives $\Gamma =|\mathbf{k}|\sum |\mathcal{M}{|}^2/(8\pi M_i^2)$. In leptonic pion decay, contracting the axial hadronic matrix element with the chiral weak charged current makes this amplitude proportional to the charged-lepton mass, proving helicity suppression.

An absorptive phase arises from physical intermediate states or rescattering in a decay amplitude. For a pair of CP symmetry conjugate reactions with otherwise symmetric dynamics, this phase is the same in both amplitudes, whereas a weak phase changes sign. Their differing transformation laws allow interference to produce a direct CP asymmetry.