Deuterium bottleneck

Light nuclei cannot accumulate until cooling makes deuterium sufficiently resistant to photodissociation, delaying nucleosynthesis after weak freeze-out.

For chemical equilibrium $D\leftrightarrow n+p$, Maxwell--Boltzmann densities and ${\mu }_D={\mu }_n+{\mu }_p$ give, after taking $m_n\simeq m_p$ and $m_D\simeq 2m_p$,Writing $X_i=n_i/n_B$, $n_B=\eta n_{\gamma }$, and $n_{\gamma }=16\pi \zeta (3)(k_{B}T{)}^3/(hc{)}^3$ givesThe very small baryon-to-photon ratio suppresses deuterium until $T$ is far below the binding-energy scale.

Increasing the baryon-to-photon ratio raises the equilibrium deuterium abundance at fixed temperature, so the deuterium bottleneck ends earlier. Fewer neutrons decay before nuclear burning, and neutron-limited helium synthesis produces a larger primordial helium mass fraction if weak freeze-out is unchanged.

Between weak freeze-out and deuterium formation, beta decay lowers the surviving free-neutron fraction.