For a spherical droplet at fixed center height above a flat equilibrium reservoir, the diffusion-capacitance analogy and sphere-plane capacitance give
At large separation, , so
The nearby reservoir increases the total flux and shortens the lifetime. The spherical-shape assumption controls the geometry; the local current density is not uniform over the surface.
The flat interface is an equilibrium reservoir with , while the droplet has the constant surface value . The exterior chemical potential satisfies the Laplace equation, tends to zero far away, and obeys these two surface values. These are exactly the electrostatic boundary conditions at a conductor for a sphere held at potential above a grounded infinite plane.
Introduce an arbitrary permittivity . In the electrostatic problem, . Therefore the diffusion-capacitance analogy gives the outward current
For an isolated sphere, its capacitance is , so . Dividing gives
Thus sphere-plane capacitance determines the evaporation enhancement. The assumed spherical shape gives the corresponding law for droplet evaporation near a planar reservoir. The local surface current is generally nonuniform, even though its total is described by a single capacitance.