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A dynode is an electrode that emits secondary electrons when struck by an incoming electron. A photomultiplier arranges successive dynodes at increasing potentials so that photoelectrons are accelerated and multiplied through a cascade.

If the mean multiplication factor per stage is $\delta$ and there are $n$ comparable stages, the idealized mean gain is ${\delta }^n$. Fluctuations in secondary emission contribute to output noise. Excessive current can disturb the electrode voltages or create space-charge effects, so gain calibration and linearity need experimental checks.

An electron multiplier amplifies a signal by accelerating incoming electrons into surfaces that emit additional secondary electrons. Repeating this process at successive stages produces a measurable charge packet from a small initial signal.

A photomultiplier adds a photosensitive input that converts incident light into a photoelectron; its dynodes then perform multiplication. In a simple equal-stage model with mean secondary yield $\delta$, $m$ stages give mean gain ${\delta }^m$. The output fluctuates because emission is stochastic, and saturation can invalidate constant gain. Multiplication increases the signal scale but cannot recreate input events that were never detected.

A mass spectrometer detector turns arriving ions into a recorded electrical signal. It is distinct from the mass analyzer that makes mass-to-charge ratio information distinguishable. The measured response can depend on collection, conversion and amplification as well as on how many ions arrived.

A Faraday cup collects electric charge directly. Ideally, a flux $\Phi$ of ions with known charge $q$ gives $I=q\Phi$. For $10^6$ singly charged positive ions per second, the current is $1.602176634\times 10^{-13}\mathrm{A}$, about $0.1602\mathrm{pA}$. Escaping secondary electrons and background currents must be accounted for when inferring particle delivery.^[ref]

An electron multiplier instead uses secondary emission to amplify the initial conversion signal. The manufacturer's detector description shows discrete dynodes, a continuous-dynode alternative, and a conversion dynode before the multiplier.^[ref] In an illustrative equal-stage model, ten stages with mean yield $\delta =4$ give mean gain $G=4^{10}=1048576$. This is a model calculation, not a measured gain for a named instrument.

Detector gain and detection efficiency answer different questions: the size of an output event and the probability of registering an arriving ion. Increasing gain cannot recover missed ions. At high signals, mass spectrometer detector saturation can also invalidate proportionality between ion delivery and recorded response. Quantitative peak comparisons therefore need a tested response range and appropriate instrument calibration, not merely a large signal.

A photomultiplier detects weak light by converting a photon into a photoelectron at a photosensitive cathode, then multiplying electrons through successive dynodes. Each impact can release several secondary electrons, and an anode collects the amplified packet as an electrical pulse.

If each of $m$ stages has mean multiplication $\delta$, the mean gain is approximately ${\delta }^m$. This amplification makes small signals measurable but does not eliminate photon shot noise or fluctuations in multiplication. Quantum efficiency controls the probability of producing an initial useful photoelectron, while dark current and background produce additional signals. Optical shielding, stable applied voltages and a blocked-light measurement are therefore essential to interpreting a weak-light count.^[ref]