The ratio of an ion's mass to its electric charge; in SI it has units . A convenient numerical mass spectrum coordinate is , with and positive integer here. This is dimensionless. Doubling at fixed mass halves , so the electric charge state must be identified before assigning an isotope.

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The mass-to-charge ratio (m/z) is a fundamental concept in mass spectrometry and ion physics. It is defined as the ratio of the mass (m) of an ion to its charge (z).