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The electric potential of a point charge $Q$ at the origin isFor the two charges forming the dipole,The first-order Taylor expansion at large $|\mathbf{x}|$ isand therefore, with the electric dipole moment $\mathbf{p}=Q\mathbf{d}$,to leading order. Taking the interaction of a second dipole with the corresponding electric field gives the stated electric dipole-dipole interaction

Let the lattice spacing be $d$ and write the central dipole asIts two horizontal neighbours have moment $p(\cos \theta ,-\sin \theta )$. For either one, the expression in parentheses, after extracting $d^{-3}$, isIts two vertical neighbours have moment $p(-\cos \theta ,\sin \theta )$, and each contributes insteadAdding all four nearest-neighbour interactions and using the Pythagorean trigonometric identity givesThe angle has cancelled, so the energy is independent of $\theta$.

Point-charge field and superposition. Coulomb's law gives the Coulomb force on a test electric charge $q_t$ a displacement $\mathbf{R}$ from a source point charge $Q$:The electric field is force per infinitesimal test charge, soIt points outward for positive $Q$ and inward for negative $Q$. For several point charges, the superposition principle adds their fields as vectors:This formula excludes the source points themselves, where the ideal point-charge field is singular.

Exact field components of the pair. PutThe displacement vectors from the positive and negative charges to the observation point are $(x-a)\hat{\mathbf{i}}+y\hat{\mathbf{j}}$ and $(x+a)\hat{\mathbf{i}}+y\hat{\mathbf{j}}$. Including the signs of the charges givesReading off both components,For example, on the perpendicular bisector $x=0$, the two $y$ components cancel and the $x$ components add toward the negative charge, checking both relative signs.

Far-field polar components. The pair's electric dipole moment points from negative to positive charge:Use polar coordinates $x=r\cos \theta$, $y=r\sin \theta$, with $\theta$ measured from that positive dipole axis. The supplied leading electric dipole field becomesTaking the dot products with the radial and angular unit vectors givesThereforeThe unit vectors for polar coordinates are orthonormal, so the magnitude isThe units are $\mathrm{N}{\mathrm{C}}^{-1}$, since the electric dipole moment has units $\mathrm{C}\mathrm{m}$.

Angular sketch and comparison. At fixed large $r$, the magnitude has period $\pi$. It is largest on the dipole axis, $\theta =0,\pi$, with value $2p/(4\pi {ϵ}_0{r}^3)$, and smallest on the perpendicular directions, $\theta =\pi /2,3\pi /2$, with value $p/(4\pi {ϵ}_0{r}^3)$. The field magnitude never vanishes at finite $r$ in this dipole approximation:

The neutral charge pair has no net electric charge, so its leading far field falls as $r^{-3}$ and depends on direction. An isolated nonzero point charge has an $r^{-2}$ field whose magnitude is isotropic, with purely radial direction. The dipole also generally has a nonzero $E_{\theta }$ component.

A molecular example is the interaction between permanent electric dipoles of hydrogen chloride molecules, whose unequal charge distributions give each molecule a nonzero electric dipole moment. The electric dipole-dipole interaction depends on their relative orientations:For two parallel dipoles pointing along their line of separation, $U=-2p_1{p}_2/(4\pi {ϵ}_0{r}^3)<0$, illustrating an attractive molecular configuration.