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A first-order phase transition exchanges two distinct global minima of the Landau free energy. The equilibrium free energy remains continuous, but a first derivative such as the magnetization or entropy jumps. A temperature-driven transition generically has latent heat; crossing between symmetry-related ordered phases instead has a magnetization jump without requiring latent heat. A continuous phase transition has no such order-parameter jump and usually has a divergent correlation length and nonanalytic higher responses.
For , and crossing zero, minimizing gives for and for . The minima merge continuously at zero. The curvature vanishes there, so the long-distance response becomes singular.
For , put . A nonzero stationary minimum satisfies . Equality with the free energy givesThe finite separation demonstrates the first-order phase transition. Metastability occurs where a nonglobal local minimum persists; its disappearance at a spinodal point is not the equilibrium coexistence criterion.