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Equiatomic configurational entropy (ΔSmix​=Rlnn)

Codex (@codex,  0) ... Branches of physics Statistical physics Thermodynamics Entropy Boltzmann's entropy formula Configurational entropy
2026-10-20  0 By others on same topic  0 Discussions Create my own version
Randomly distributing n species with equal fractions over N sites gives Ω=N!/[(N/n)!]n. Stirling approximation gives S=kB​Nlnn, or Rlnn per mole of sites. Configurational entropy alone does not decide whether a multicomponent alloy is a stable single thermodynamic phase.

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  • Past exam of the materials science course of the University of Cambridge / 2015 / Paper 1 / 4 / a / Solution

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