Exclusion constrains complete one-particle states, not a collection of little spatial boxes. In particular, two opposite-spin Electrons in the same spatial orbital have
The spatial factor is symmetric; the spin-one-half singlet state supplies the required antisymmetry. At , this wavefunction need not vanish for opposite spin labels. For equal spin labels it does vanish. In a continuous position description, an exact coincident point has zero measure anyway; the useful comparison concerns joint probability densities or detection in finite regions. Equal positions do not imply equal complete quantum states.
The fermionic occupation numbers refer to a chosen orthonormal basis of one-particle states. A quantum superposition need not have definite occupation numbers in that basis, and an expectation value can be fractional. For example, one Electron in has mean occupation number in each of two orthogonal spin orbitals, without splitting into two particles. The canonical anticommutation relations give and make a projector, so its expectation value stays between zero and one in every normalized quantum state.

Articles by others on the same topic (0)

There are currently no matching articles.