Past exam of the chemistry A course of the University of Cambridge 2021 Paper 2 A9 a iii Solution 2026-10-20
Let be the total two-dimensional area. There are wavevector states per reciprocal-space area per spin. Including spin degeneracy two and filling a disk givesFor areal number density this yieldsThe disk is centred at zero wavevector, and its boundary is a fermi circle. Omitting the two spin states would incorrectly double the energy inferred for a given number density.
Past exam of the chemistry A course of the University of Cambridge 2021 Paper 2 A9 c ii Solution 2026-10-20
For one electron per square cell, , soNumerically, exceeds , so the fermi circle lies entirely inside the first Brillouin zone.
The state-counting explanation is that a spin-degenerate band has two electron states per primitive cell. One electron per cell therefore occupies half of that band. In the circular free-electron approximation the occupied reciprocal-space area isA disk of that area fits inside this square: its radius is less than the distance to an edge. Half filling alone is not a shape-independent theorem that every possible Fermi surface must avoid every zone boundary; the square geometry and circular free-electron dispersion make the statement true here.
Past exam of the chemistry A course of the University of Cambridge 2023 Paper 2 A9 b v Solution 2026-10-20
For an isotropic two-dimensional free-electron model, the occupied states form a disk centered at the reciprocal origin. Its Fermi circle first touches a zone side when its radius equals half the distance to a nearest reciprocal point:The contact points have coordinates with all four sign combinations. The distance to a zone vertex is , which is larger; that distance would describe contact with a corner after the circle had already crossed a side.