Particle-conserving displacement of a Fermi circle Created 2026-10-25 Updated 2026-11-05
Translating a Fermi circle of radius by preserves its area. For , its radial displacement from the original centre is the displayed expression. Its Taylor expansion is . The second-order term cancels the apparent area increase from the first-order shape: . This distinction matters when converting a grand-potential variation into a fixed-particle number energy change.
Past exam of the chemistry A course of the University of Cambridge 2021 Paper 2 A9 a iii Solution 2026-10-20
Let be the total two-dimensional area. There are wavevector states per reciprocal-space area per spin. Including spin degeneracy two and filling a disk givesFor areal number density this yieldsThe disk is centred at zero wavevector, and its boundary is a fermi circle. Omitting the two spin states would incorrectly double the energy inferred for a given number density.
Past exam of the chemistry A course of the University of Cambridge 2021 Paper 2 A9 c ii Solution 2026-10-20
For one electron per square cell, , soNumerically, exceeds , so the fermi circle lies entirely inside the first Brillouin zone.
The state-counting explanation is that a spin-degenerate band has two electron states per primitive cell. One electron per cell therefore occupies half of that band. In the circular free-electron approximation the occupied reciprocal-space area isA disk of that area fits inside this square: its radius is less than the distance to an edge. Half filling alone is not a shape-independent theorem that every possible Fermi surface must avoid every zone boundary; the square geometry and circular free-electron dispersion make the statement true here.
Past exam of the chemistry A course of the University of Cambridge 2023 Paper 2 A9 b v Solution 2026-10-20
For an isotropic two-dimensional free-electron model, the occupied states form a disk centered at the reciprocal origin. Its Fermi circle first touches a zone side when its radius equals half the distance to a nearest reciprocal point:The contact points have coordinates with all four sign combinations. The distance to a zone vertex is , which is larger; that distance would describe contact with a corner after the circle had already crossed a side.
Past exam of the condensed matter physics course of the University of Oxford 2012 4 d Solution 2026-10-25
For one electron per primitive unit cell, the areal number density is . The Fermi circle has radius . The nearer first-zone boundary is , because . The circle protrudes precisely whenAt equality the Fermi surface only touches the boundary. Crossing an extended-zone boundary alone does not make a gap: the free electron gas remains metallic when the ionic periodic potential is neglected.
The shifted Fermi circle satisfies . Its radial boundary at polar angle is the positive solution of . Thus, for ,and its leading Taylor expansion isForward-pointing momenta gain occupied states and backward-pointing momenta lose them. With the paper's explicitly reversed Heaviside step function convention, ; consequentlywith a positive leading sign.
For the later quadratic energy calculation it is useful to distinguish the first-order shape from exact particle number conservation. The particle-conserving displacement of a Fermi circle hasThe second-order inward correction cancels the apparent area increase one would obtain by treating as exact.
