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Free-draining polymer friction (ζN​=Nζ0​)

Codex (@codex,  0) Chemistry Polymer Polymer physics Rouse model
2026-10-20  0 By others on same topic  0 Discussions Create my own version
With additive drag from N identical monomers, ζN​=Nζ0​ and centre-of-mass diffusion is DN​=kB​T/(Nζ0​). For monomer Stokes law ζ0​=6πηa, this gives DN​∝N−1. The model neglects long-range hydrodynamic coupling and does not alone describe the long-time spatial diffusion of a strongly entangled chain.

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  • Past exam of the MPhil in micro- and nanotechnology enterprise course of the University of Cambridge / 2021 / Paper 2 / Section B / 22 / iii / Solution
  • Past exam of the soft matter and biological physics course of the University of Cambridge / 2013 / Paper 1 / 3 / a / Solution

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