Frequency-selective spin control

Individual quantum control of spins by exploiting different resonance frequencies. A sufficiently narrow-band radio frequency pulse can predominantly affect one resonance when the separation is large compared with the excitation bandwidth and coupling effects are accounted for. Equal resonance frequencies remove this frequency-based distinction. Whether individual gates remain possible then depends on other available interactions, spatial resolution, or differences in control coupling; frequency equality alone is not a universal impossibility theorem.

Let $S$ be the SWAP gate. If the drift Hamiltonian operator and every allowed control Hamiltonian operator commute with $S$, every reachable time-evolution operator also commutes with $S$. Indeed, $SUS$ satisfies the same initial-value Schrödinger equation as $U$ and starts at $I$, so uniqueness gives $SUS=U$. Yet $S(Z\otimes I)S=I\otimes Z\ne Z\otimes I$. An individual Pauli Z gate is consequently unavailable within that symmetric control model. Equal nuclear resonances, isotropic exchange interaction, and identical coupling to a common homogeneous radio frequency field provide an example. An added interaction that breaks this symmetry can remove the obstruction.