In Giant Rydberg Excitons in Cuprous Oxide by Tomasz Kazimierczuk and others, a polished copper(I) oxide crystal was mounted without strain at . A tunable single-frequency dye laser scanned photon energy; balanced detection compared transmitted light with a reference beam. Transmission dips resolved spectral lines assigned to bound excitons through principal quantum number . Their convergence towards an unbound threshold supports a hydrogen-like internal series, with small systematic deviations.[ref]
Controls mattered: restricting broadband illumination improved resolution of high- excitons; lowering laser power or expanding its spot reduced interaction-induced suppression. Balanced detection suppressed source fluctuations. The measurement probes optical resonances, not individual Electron-electron hole trajectories or directly imaged radii. Electric-dipole selection rules favor P-envelope states in this material, unlike the hypothetical permitted lowest-state transition above. Finite resolution and crystal inhomogeneity affect spectral lines; the inferred binding series requires a continuum threshold and a model.[ref]