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For a graded vector space $V$, $\mathrm{Sym}(V)$ is the quotient of the tensor algebra by $uv-(-1{)}^{|u||v|}vu$. Over $\mathbb{Q}$ it is polynomial on even-degree basis elements and exterior on odd-degree ones. With each generator primitive, it is a graded cocommutative Hopf algebra. Its primitive subspace is exactly $V$: applying the diagonal to a polynomial of symmetric length greater than one produces mixed terms, or equivalently the polynomial's formal derivatives cannot all vanish in characteristic zero. This is the associated graded algebra in the graded Poincaré–Birkhoff–Witt theorem.

Use shifted degreesIts graded Lie bracket is the sign-adjusted Whitehead bracket from Question 2, equivalently the Samelson product on loops. This regrading is essential: the geometric bracket has degree minus one in the unshifted sphere grading. A free graded Lie algebra on a graded vector space $V$ means $\mathbb{L}(V)$ with the universal extension property for linear maps from $V$ to any graded Lie algebra.

Here are the general results used. The Bott–Samelson theorem says that, for a connected based CW complex $X$, the inclusion $X\to \Omega \Sigma X$ induces an isomorphism of graded algebraswith the Pontryagin product. The Milnor–Moore theorem says that for simply connected $Y$, rational loop Hurewicz homomorphism identifies $L_Y$ with the primitives of that loop-homology Hopf algebra and induces $U(L_Y)\cong H_{\ast }(\Omega Y;\mathbb{Q})$. The graded Poincaré-Birkhoff-Witt theorem identifies the associated graded algebra of $U(L)$, for its word-length filtration, with the graded symmetric algebra on $L$; hence its primitive elements of a Hopf algebra are exactly $L$ over $\mathbb{Q}$. Finally the rational Whitehead theorem identifies rational homology equivalences of simply connected CW complexes with rational homotopy equivalences. Rationalization of a topological space induces the corresponding isomorphisms of loop-space homotopy and rational homology.

Suppose first $Y$ has the rational homotopy type of $\Sigma X$. A reduced suspension is simply connected when $X$ is connected; a disconnected $X$ has $H_1(\Sigma X;\mathbb{Q})={\tilde{H}}_0(X;\mathbb{Q})\ne 0$, so it cannot have the rational homology of the simply connected $Y$. Put $V={\tilde{H}}_{\ast }(X;\mathbb{Q})$, in strictly positive degrees. Bott–Samelson theorem gives $H_{\ast }(\Omega Y;\mathbb{Q})\cong T(V)$ as an algebra. To deduce freeness of the primitive Lie algebra, its coproduct must also be considered: the initial Bott–Samelson theorem generators can have reduced-diagonal terms when $X$ has nontrivial cup products.

By Milnor–Moore theorem write this Hopf algebra as $U(L_Y)$. Its algebra indecomposables satisfyThe first identity follows from the enveloping relation: after all positive products are killed, every bracket is killed and no additional linear relation is introduced. Hence each homogeneous basis vector of $V$ has a primitive representative in $H_{\ast }(\Omega Y;\mathbb{Q})$. Choose such representatives $p_v$. Sending $v$ to $p_v$ defines an algebra map from $T(V)$ to itself whose effect on indecomposables is the identity. It is an isomorphism: $p_v=v+$ decomposable terms, and every factor in those terms has smaller positive degree than $v$. Degree induction solves recursively for each original generator and constructs the inverse. This works even with arbitrarily many generators in a degree.

Equip the source tensor algebra with primitive generators. The map is now a Hopf-algebra isomorphism, because the chosen images are primitive. The primitives in this tensor Hopf algebra are exactly $\mathbb{L}(V)$: $U(\mathbb{L}(V))=T(V)$ by the two universal properties, and the graded Graded Poincaré–Birkhoff–Witt theorem gives its primitive subspace. Consequently $L_Y\cong \mathbb{L}(V)$, proving the forward direction without assuming a primitive coproduct for the original generators.

Conversely suppose $L_Y\cong \mathbb{L}(W)$ for a positively graded $W$. Choose a homogeneous basis $w_{\lambda }$ of $W$. Represent its corresponding homotopy class by a based sphere map $S^{|w_{\lambda }|+1}\to Y_{\mathbb{Q}}$, and combine these maps intoThe wedge sum is a reduced suspension, namely $Z=\Sigma ({\bigvee }_{\lambda }{S}^{|w_{\lambda }|})$. The preceding direction, applied to this wedge sum, gives its free rational homotopy Lie algebra on the sphere inclusions. Indeed these particular tensor generators are primitive because the reduced diagonal of each sphere is zero, and loop Hurewicz homomorphism sends the adjoint sphere inclusion to that generator. Naturality of the bracket shows that $F_{\ast }$ sends the free generating basis to the prescribed free generating basis of $L_Y$. It is therefore an isomorphism of free graded Lie algebras, hence an isomorphism in every rational homotopy degree. The rational Whitehead theorem makes $F$ a rational homotopy equivalence. This proves the reverse implication and also shows that a wedge sum of spheres can be chosen as the reduced suspension.

For every chosen connected $X$ with $Y{\simeq }_{\mathbb{Q}}\Sigma X$, the required algebra statement is precisely the Bott–Samelson theorem isomorphism, transported along rational homotopy equivalence:Multiplication is concatenation of tensors and the degree-zero tensor is the unit. All freeness assertions here are graded, with the Koszul signs described above.