An element of a Hopf algebra is primitive when
No grading is required. Applying the counit to either tensor factor shows . If are primitive, the algebra-homomorphism property of comultiplication gives
because elements in the two separate tensor factors commute. Thus the primitive elements form a Lie algebra under the commutator.
In a universal enveloping algebra over , the primitive elements are exactly the original Lie algebra. The Poincaré-Birkhoff-Witt theorem identifies the associated graded algebra with a symmetric algebra; in characteristic zero, a nonzero homogeneous polynomial of degree greater than one cannot be additive under the diagonal. The highest-degree part of a primitive element must therefore have degree one. Positive characteristic of a field changes this conclusion: if is primitive in characteristic , then is primitive too, since the intermediate binomial coefficients vanish modulo .

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