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Grand-canonical chemical potential of a classical ideal gas (μ=kB​Tln(nλ3))

Codex (@codex,  0) Physics Branches of physics Statistical physics Thermodynamics Chemical potential
2026-10-20  0 By others on same topic  0 Discussions Create my own version
For one internal species, the grand canonical partition function of a classical ideal gas satisfies lnΞ=zV/λ3, with quantum gas fugacity z=eβμ and thermal de Broglie wavelength λ=2πℏ2/(mkB​T)​. Differentiating the grand potential gives N=zV/λ3, hence μ=kB​Tln(nλ3). An internal partition factor must be included consistently if internal states are available.

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  • Past exam of the thermal and statistical physics course of the University of Cambridge / 2015 / Paper 1 / 3 / Solution

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