Gravimetric dilution factor 2026-11-05
The gravimetric dilution factor is the ratio of final mixture mass to the stock mass used in a gravimetric dilution:Here is added diluent mass and is the retained stock mass fraction. For a diluent containing none of the component being measured, mass conservation gives final component mass fraction . This mass-based relation avoids assuming that liquid volumes are additive. Its uncertainty follows from the same input masses and their covariance as the uncertainty of a gravimetric dilution.[ref]
For an original two-step example, combine of stock with of diluent, giving . After complete mixing, transfer of that mixture and add of diluent, giving . The combined gravimetric dilution factor isIf the original stock has component mass fraction , the first mixture has and the final mixture . The transferred gram contains of the component; dividing by the final checks the result. This calculation requires a representative, homogeneous transferred portion and no component loss.
Massic activity 2026-11-05
Massic activity is a sample's radioactive activity divided by its mass:Its SI unit is the becquerel per kilogram, . State both the material included in the denominator and the time to which the activity refers. For a solution, the mass of the complete sample is different from the mass of its radioactive constituent.[ref]
Massic Activity Ratios of the NBS/NIST Tritiated-Water Standards Issued Between 1954 and 1999 by L. L. Lucas. Abstract, explicit definition as sample activity divided by sample mass
For an own bookkeeping example, suppose a sample has total activity and total mass at a specified instant. ThenImagine adding nonradioactive material so that the total mass becomes , with no loss of activity and no relevant elapsed decay time. The total activity remains , butA lower massic activity therefore does not by itself demonstrate radioactive decay or loss of radioactive atoms: the denominator can change.
Time introduces a separate effect. For a fixed sample mass and a single decaying constituent with radioactive decay constant , use the usual mean exponential law:After one half-life, the massic activity halves under those assumptions. Comparing standards requires either a common reference time or the appropriate decay correction. Additional radioactive constituents, production of daughter activity or changing sample mass require a correspondingly different model.
The quantity also supports experimental cross-checks. In a 2000 study, L. L. Lucas compared massic-activity ratios of available NBS/NIST water standards containing tritium, issued between 1954 and 1999. Liquid scintillation counting supplied measured ratios; where the records allowed it, gravimetric dilution supplied independently calculated ratios. The paper reports agreement within the stated measurement uncertainties.[ref]
Massic Activity Ratios of the NBS/NIST Tritiated-Water Standards Issued Between 1954 and 1999 by L. L. Lucas. Abstract, available standards, liquid-scintillation comparison and gravimetric dilution factors
This compares two kinds of evidence: radioactive counting with its detector response, and mass-based preparation records. A measured count rate still needs a detection efficiency and measurement model before it becomes an activity estimate. Dividing a detector's raw counts by sample mass alone is not the definition of massic activity. Also distinguish radioactive activity concentration, which uses volume rather than mass in the denominator.