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Let $X_j$ be the number of failures in mix $j$. The total observed failures are $32+2(12)+3(2)+4(1)=66$ among $600$ blocks. Equal marginal failure probabilities give $E(X_j)=6p$, regardless of dependence within a mix. Thus the unbiased estimator based on grouped Bernoulli failure counts isFor a conventional binomial confidence interval, additionally assume independent block outcomes. Then the total $S$ has binomial distribution $\mathrm{Bin}(600,p)$ and the estimated standard error is $\sqrt{\hat{p}(1-\hat{p})/600}=0.01277$. The normal approximation gives the approximate 95 percent intervalOne can instead obtain an exact, generally conservative binomial interval by solving $P_{p_L}(S\ge 66)=0.025$ and $P_{p_U}(S\le 66)=0.025$ for the two endpoints. These equations invert binomial tail tests.

Equal marginal probabilities alone do not imply independent blocks. If the mixes are independent but blocks within a mix can be dependent, use the sample variance of the 100 counts. Here $\sum X_j^2=114$ and $\overline{X}=0.66$, so $s_X^2=(114-100(0.66{)}^2)/99=0.7115$. The estimated variance of $\hat{p}=\overline{X}/6$ is $s_X^2/(100\times 36)$; its standard error is $0.01406$, giving the large-sample interval approximately $(0.0824,0.1376)$. If even between-mix independence is absent, no stated model justifies either numerical coverage claim. The estimate remains unbiased, but the uncertainty calculation needs its sampling assumptions.