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In a spherical self-gravitating equilibrium with positive mass density, $d\psi /dr=GM(r)/r^2>0$ away from the center. Thus $r$ can locally be replaced by $\psi$, so both $p(r)$ and $\rho (r)$ can be expressed as functions of $\psi$. Hydrostatic equilibrium further givesSince $p$ decreases outward wherever $\rho >0$, eliminating $\psi$ gives a barotropic equation of state along this equilibrium. This is a relation describing its structure; it does not require all thermodynamic perturbations of an arbitrary material to be barotropic.

For $p=K{\rho }^{1+1/n}$, integrate the polytropic enthalpy balance $dp/\rho =-d\psi$:For a finite-radius zero-pressure boundary with $K>0$ and $n>0$, $\rho (R)=0$ and therefore ${\psi }_T=\psi (R)$. With the gravitational potential zero at infinity, an isolated sphere has ${\psi }_T=-GM/R$. It is an integration constant tied to that boundary, not necessarily a zero of the gravitational potential.

Put $\theta =(\rho /{\rho }_c{)}^{1/n}$ and $\xi =\alpha r$, with ${\alpha }^2=4\pi G{\rho }_c^{1-1/n}/[(n+1)K]$. The preceding relation gives $\psi ={\psi }_T-(n+1)K{\rho }_c^{1/n}\theta$. Substitution into the spherical gravitational Poisson equation yields the Lane-Emden equationLet ${\xi }_1$ be the first zero of the regular Lane-Emden function and $Y_n=-{\xi }_1^2{\theta }^{\prime }({\xi }_1)>0$. Then the Lane-Emden mass formula and radius areFor a common fixed polytropic index with a finite first zero, their scalings areThe usual regular zero-pressure models have a finite first zero for $0<n<5$; the $n=5$ model has infinite radius, so a finite-radius formula cannot simply be applied to it.

For an ideal gas of fixed composition, $T_c\propto K{\rho }_c^{1/n}$. Consequently homologous polytropes at fixed central temperature have $K\propto {\rho }_c^{-1/n}$ and both $M,R\propto {\rho }_c^{-1/2}$, recovering $M\propto R$. The common central temperature, composition and dimensionless structure are the relevant assumptions. Keeping $K$ fixed instead gives the different polytropic mass-radius relation, and no finite index makes its generic fixed-$K$ exponent exactly one.

For adiabatic monatomic hydrogen, $\gamma =5/3$ and $n=3/2$. At a common fixed specific entropy, hence common $K$, the same relations giveHere $\bar{\rho }=3M/(4\pi R^3)$, and the omitted constant in the last relation depends on $K$. A population with different cloud entropies need not follow that mass sequence.

Efficient radiative cooling in molecular clouds prevents compression from forcing the temperature upward as steeply as in an adiabatic monatomic gas. Rotational transitions of molecules and radiation by dust provide low-temperature cooling channels; which dominates depends on composition, opacity and temperature. It is therefore possible to assemble dense massive cold clouds while disposing of compressional heat. This explains the direction of the idealized comparison, rather than proving a universal cloud-mass cutoff.

For a common isothermal sound speed $c_T$, a spherical isothermal equilibrium has $GM/R$ equal to $c_T^2$ times a dimensionless structural factor. Holding that factor fixed gives the homologous isothermal mass-radius relationFor example, the singular isothermal sphere has $M(R)=2c_T^{2}R/G$. A regular finite cloud requires a pressure-confined isothermal sphere or another outer boundary: an unconfined isothermal sphere does not end at a finite vacuum radius. Equal temperature alone, while allowing arbitrary truncation or density contrast, does not make the coefficient universal.