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The curve is symmetric in both coordinate axes and under interchange of $x$ and $z$. Its shape, including its eight inflection points, is:

Writing $r^2=x^2+y^2$, the surface of revolution has equationLetIts gradient isIf this vanished, then $r^2\in \{0,1\}$ and $z^2\in \{0,1\}$, but at such a point $(r^2-1{)}^2+(z^2-1{)}^2\le 2$, not five. Hence zero is a regular value, and the regular level set theorem shows that $S=F^{-1}(0)$ is a smooth embedded surface.

For a surface of revolution, the two principal curvatures are the curvature of the meridian and the normal curvature of a parallel. Along $r=1$,so the normal is vertical in the meridian plane and the parallel principal curvature vanishes. Therefore the Gaussian curvature, the product of the principal curvatures, is zero there.

These are not the only zero-curvature points. The meridian itself has inflection points, at which its principal curvature vanishes. Setting $u=r^2$ and $v=z^2$, their positive squared coordinates satisfyBesides interchanging $u$ and $v$, the solution is approximatelyEach corresponding meridian inflection point sweeps out another circle on $S$, so $r=1$ does not exhaust the zero set of the Gaussian curvature.