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Liquid scintillation counting measures radiation through light produced in a liquid scintillator containing the radioactive sample. Energy deposited in the medium leads to optical emission, which photomultipliers detect as pulses. The apparatus is a scintillation counter, but the measured pulse rate still needs a model connecting it to radioactive activity.^[ref]

In an idealized one-count-per-decay model with background subtracted and other corrections negligible,where $A$ is radioactive activity and $\epsilon$ is detection efficiency. A hypothetical net rate of $100{\mathrm{s}}^{-1}$ with $\epsilon =0.40$ corresponds to $A=250\mathrm{Bq}$. At the same activity, an efficiency of $0.20$ would produce only $50{\mathrm{s}}^{-1}$. A smaller count rate need not mean that fewer decays occur.

A motivating measurement example is L. L. Lucas's comparison of tritium-containing water standards. Liquid scintillation counting supplied massic activity ratios that could be compared with independently recorded mass-based dilutions. Agreement within stated measurement uncertainties supports consistency of the standards; it does not turn the counting apparatus into an uncertainty-free activity meter.^[ref]

Massic activity is a sample's radioactive activity divided by its mass:Its SI unit is the becquerel per kilogram, $\mathrm{Bq}\mathrm{k}{\mathrm{g}}^{-1}$. State both the material included in the denominator and the time to which the activity refers. For a solution, the mass of the complete sample is different from the mass of its radioactive constituent.^[ref]

For an own bookkeeping example, suppose a sample has total activity $A=60\mathrm{Bq}$ and total mass $m=0.020\mathrm{kg}$ at a specified instant. ThenImagine adding nonradioactive material so that the total mass becomes $0.040\mathrm{kg}$, with no loss of activity and no relevant elapsed decay time. The total activity remains $60\mathrm{Bq}$, butA lower massic activity therefore does not by itself demonstrate radioactive decay or loss of radioactive atoms: the denominator can change.

Time introduces a separate effect. For a fixed sample mass and a single decaying constituent with radioactive decay constant $\lambda$, use the usual mean exponential law:After one half-life, the massic activity halves under those assumptions. Comparing standards requires either a common reference time or the appropriate decay correction. Additional radioactive constituents, production of daughter activity or changing sample mass require a correspondingly different model.

The quantity also supports experimental cross-checks. In a 2000 study, L. L. Lucas compared massic-activity ratios of available NBS/NIST water standards containing tritium, issued between 1954 and 1999. Liquid scintillation counting supplied measured ratios; where the records allowed it, gravimetric dilution supplied independently calculated ratios. The paper reports agreement within the stated measurement uncertainties.^[ref]

This compares two kinds of evidence: radioactive counting with its detector response, and mass-based preparation records. A measured count rate still needs a detection efficiency and measurement model before it becomes an activity estimate. Dividing a detector's raw counts by sample mass alone is not the definition of massic activity. Also distinguish radioactive activity concentration, which uses volume rather than mass in the denominator.