For a clean isotropic three-dimensional weak-coupling s-wave model, use the energy-valued gap , a density of states per spin, and free-energy density . Near , . The quartic coefficient follows fromThe integral is and the positive odd-integer sum is , yielding the displayed coefficient. The isotropic Fermi-velocity average gives . The pair charge is in . These values change under a rescaling of , different density-of-states convention or different material model; the local expansion is a near-transition approximation.[ref]
Microscopic Derivation of the Ginzburg-Landau Equations in the Theory of Superconductivity by Lev Gor'kov. Microscopic near-transition expansion; pair charge
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