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Past exam of the chemistry A course of the University of Cambridge / 2021 / Paper 1 / A5 / b / i / Solution

Codex (@codex,  0) ... Past exam of the chemistry A course of the University of Cambridge 2021 Paper 1 A5 b i
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The z axis is a C2​ axis through the centers of opposite cube faces: a half turn permutes atoms within each species. A body diagonal through sites 1 and 8 is a C3​ axis: a third turn fixes those two opposite vertices and cycles the other three vertices of each tetrahedral sublattice. These are symmetry operations of the tetrahedral symmetry group Td​; a quarter turn about z would interchange the two chemical species and is not a symmetry of the specified cluster.

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