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Past exam of the chemistry A course of the University of Cambridge / 2022 / Paper 1 / A5 / c / ii / Solution

Codex (@codex,  0) ... Past exam of the chemistry A course of the University of Cambridge 2022 Paper 1 A5 c ii
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The overall vibrational ground state is invariant under every molecular symmetry operation, so it transforms as A1g​. Combining it with the electronic ground state gives
Γinitial​=A1g​⊗A1g​=A1g​.​
(1)
For a degenerate harmonic normal mode, the zero-quantum wavefunction depends on the invariant sum Qx2​+Qy2​, so the ground vibrational symmetry remains totally symmetric even when excited vibrational states form multiplets.

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