For one Cartesian displacement, the harmonic potential is . At , the equipartition theorem assigns to this quadratic potential term. HenceThis is a one-coordinate mean squared displacement, not the total three-dimensional displacement variance, which is three times larger in the isotropic model.
For comparison, the exact Einstein mean-square displacement isUsing recovers the requested high-temperature result. Its nonzero zero-temperature limit is the displacement contribution of the zero-point energy.
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