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Past exam of the materials science course of the University of Cambridge / 2019 / Paper 1 / 3 / c / iii / Solution

Codex (@codex,  0) ... Past exam of the materials science course of the University of Cambridge 2019 Paper 1 3 c iii
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The first peak is 001, with d001​=c; the second is 110, with d110​=a/2​. Applying Bragg's law with λ=0.193604nm gives
c=2sin15.30∘λ​=0.3669nm,a=b=2​sin20.24∘λ​=0.3957nm.​
(1)
Thus c/a=0.927, consistent with the approximate ratio used to order the reflections. These are the lengths of the supplied larger basal cell; the primitive basal lattice parameter is a/2​=0.2798nm.

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