Past exam of the mathematics course of the University of Cambridge / 2002 / iii / Paper 71 / 2 / c

Above the transition,for $g_{\ast }\sim 100$. The ratio increases during cooling, rather than at higher temperature. A GUT transition at $T_c\sim 10^{15}$–$10^{16}$ GeV occurs well above this scale, so the interaction is too slow to establish or maintain thermal equilibrium throughout $T>T_c$. In fact its integrated interaction probability from an arbitrarily high temperature down to $T_c$ is at most of order $T_{\mathrm{eq}}/T_c\ll 1$, since $dt=-dT/(HT)$.

An initial Fermi-Dirac distribution with zero chemical potential therefore cannot be assumed from this high-temperature rate alone. If imposed initially and collisionlessly redshifted while the particles are massless, its thermal-looking form can persist, but this is not dynamically maintained thermal equilibrium. Other initial states can remain nonthermal. This is the thermalization temperature for a massless gauge mediator.

The below-transition rate stipulated in the model has $\Gamma /H=(T/T_D{)}^3$. If $T_c\gg T_D$ and it includes efficient number-changing reactions, it can restore chemical equilibrium after the transition and erase the initial-state memory, making the estimates in a and b applicable. If it only equilibrates momenta, or if reheating never populates the relevant range, the thermal relic calculation must be reconsidered.