Assume standard radiation-dominated expansion, negligible chemical potential, one neutrino helicity and one antineutrino helicity, and a stable species with no later entropy injection. Use natural units and unreduced Planck mass . The relativistic energy density is . The Friedmann equation then givesFor thermal decoupling in cosmology, equate the interaction rate to :This order-of-magnitude estimate assumes the supplied rate law remains applicable there.
A decoupled relativistic species cools as , while annihilations heat the coupled bath. Treat the supplied high-temperature count as the remaining bath's entropy count, approximately equal to its energy count. Cosmological entropy conservation down to ordinary neutrino decoupling givesSubsequent electron-positron annihilation in cosmology heats photons but neither neutrino population. Therefore the two-stage entropy dilution of an early-decoupled neutrino givesThe ordinary Cosmic neutrino background has . If the rounded count instead includes the new two helicities, the remaining bath count is ; this changes the answer only slightly, to about . Keeping the extra species' entropy separate is essential in either convention.
For the two relativistic fermion states, . Photon and three standard neutrino species have present entropy degrees of freedom, referred to ,Writing , the fractional entropy of a relativistically decoupled species isThus approximately 1.7% of the thermal particle entropy is in the new neutrinos and antineutrinos. If counts all states before the new decoupling, the fraction is . These are the same rounded estimate. The question concerns the radiation/relic thermal entropy budget; it does not supply a model for entropy in later black holes or other gravitational structures.
If has a small mass but decoupled relativistically, its comoving particle number is still conserved. The relativistic-neutrino number-density ratio givesOnce nonrelativistic, . The density bound on a relativistically decoupled massive relic is thereforeUsing the standard present photon abundance and critical-density normalization, this is approximately , where is the present Hubble normalization, not a magnetic field. A stable relic must not exceed the permitted matter density; for example, if , even assigning all matter to it gives only an order- mass ceiling.
A stronger restriction can follow from neutrino free streaming and the observed formation of large-scale structure of the universe: a light thermal population acts as hot rather than cold dark matter, erasing structure below its streaming scale. If at most a fraction of the matter may be in this population, replace the overclosure ceiling by . The allowed fraction is observational input and is not supplied, so the paper does not determine a unique tighter mass limit. A species still relativistic today is radiation rather than matter; its contribution to the effective number of neutrino species is , and must instead satisfy the radiation-density constraints. These conclusions assume stable thermally populated states; decay or nonstandard entropy histories change the bounds.
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