The weak-conversion rate per expansion time falls as . Below the stated threshold it becomes less than one, so neutron-proton interconversion cannot track the rapidly changing equilibrium ratio: cosmological weak freeze-out occurs. Free neutrons subsequently decay, reducing their abundance until nuclei can survive photodissociation. Once the deuterium bottleneck is passed, nuclear reactions rapidly assemble neutrons into the strongly bound helium-4 nucleus. The short available time, low density and missing stable mass-five and mass-eight nuclei impede extensive production of heavier nuclei, leaving nearly all surviving neutrons in helium.
If just before helium formation, each helium nucleus uses two neutrons and two protons, so . Neglecting binding-energy corrections to nuclear masses,The remaining protons mainly become hydrogen. Counting all four helium nucleons, rather than only the captured neutrons, is essential to this mass fraction.
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